You may have thought that the probability would be $\displaystyle\frac{{1}}{{5}}\usepackage{cmbright}\Huge\$ because there are five sections. This would be the case if the sections were equal in size, but they are not. The probability of pointing to red is more than $\displaystyle\frac{{1}}{{5}}\usepackage{cmbright}\Huge\$ because red takes up more than $\displaystyle\frac{{1}}{{5}}\usepackage{cmbright}\Huge\$ of the circle.